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Nomenclature of Coordination Compounds

a For the com...

Question

(a) For the complex $[F e (C N)_{6}]^{4 -}$ , write the hybridisation, magnetic character and spin type of the complex. (At. number: Fe=26)
(b) Draw one of the geometrical isomers of the complex $[C o (e n)_{2} C l_{2}]^{+}$ which is optically active.

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Solution

(a) Hybridisation of $[F e (C N)_{6}]^{4 -}$ is $d^{2} s p^{3}$ , the complex is diamagnetic.

(b)

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Q. (a) For the complex

[F e (H_{2} O)_{6}]^{+ 3}

, write the hybridisation, magnetic character and spin of the complex. (At. number : Fe = 26)
(b) Draw one of the geometrical isomers of the complex

[P t (e n)_{2} C l_{2}]^{+ 2}

which is optically inactive.

Q. (a) For the complex

{[F e {(C N)}_{6}]}^{3 -}

, write the hybridization type, magnetic character and spin nature of the complex. (Atomic number :

F e = 26

).
(b) Draw one of the geometrical isomers of the complex

{[P t {(e n)}_{2} {C l}_{2}]}^{2 +}

which is optically active.

Q. Write IUPAC name of the complex

[P t (e n)_{2} C l_{2}]

. Draw structures of geometrical isomers for this complex.

Q. For the given complex

{[C o {C l}_{2} (e n) {({N H}_{3})}_{2}]}^{+}

, the number of geometrical isomers, the number of optical isomers and total number of isomers of all type possible respectively are:

Q. For the given complex

[C o C l_{2} (e n) (N H_{3})_{2}]^{+}

, the number of geometrical isomers and the number of optical isomers respectively are:

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