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Question

(a) For the complex [Fe(H2O)6]+3, write the hybridisation, magnetic character and spin of the complex. (At. number : Fe = 26)
(b) Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]+2 which is optically inactive.

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Solution

(a) Hybridisation-sp3d2, magnetic character- paramagnetic and have octahedral geometry.
(b) The geometrical isomer is shown in the diagram. Trans isomer of [Pt(en)2Cl2]+2 shows no optical activity.

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