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Question

A gas expands from a volume of 3.0dm3 to 5.0dm3 against a constant external pressure of 3.0 atm. The work done during the expansion is used to heat 10.0 mL of water of temperature 290.0 K. Calculate the final temperature of water (specific heat of water =4.184 J g1K1).

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Solution

Work done =PΔV=(3×2)L.atm=6 L.atm=607.8 J
where,
ΔV=53=2L

Heat lost = Heat gained by H2O=msΔt
Δt=607.810×18×4×4.18=0.808 KTf=290+0.808=290.808K

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