A gas expands isothermally against a constant external pressures of 1 atm from a volume of 10dm3 to a volume of 20dm3. It absorbs 800 J of thermal energy from its surroundings. Calculate the change in internal energy (ΔE).
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Solution
△T=0 (isothermal process).
Internal energy change (△E)=Q+W=nCV△T
But as △T=0,
Internal energy change (△E)=nCV△T=0
Therefore, for isothermal process, the change in internal energy (△E) is always zero.