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Question

A gas formed by the action of alcoholic KOH on ethyl iodide decolourises alkaline KMnO4. The gas is :

A
C2H6
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B
CH4
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C
C2H2
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D
C2H4
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Solution

The correct option is D C2H4
In presence of alcoholic KOH, ethyl iodide undergoes dehydrohalogenation, to form ethylene C2H4. Ethylene decolourises alkaline KMnO4.

Alkaline KMnO4 is called Baeyer's reagent and is reduced to MnO2 by ethylene.

C2H5Ialc.KOH−−−−−−−−−−−−DehydrohalogenationC2H4

CH2=CH2+alkalineKMnO4CH2(OH)CH2OH

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