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Question

A gas is enclosed in a cylinder with a movable friction less piston. Its initial thermodynamic state at pressure Pi=105Pa and volume Vi=103m3 changes to a final state at Pf=(1/32)×105Pa and Vf=8×103m3 in an adiabatic quasi-static process, such that P3V5=constant. Consider another thermodynamic process that brings the system from the same initial state to the same final state in two steps: an isobaric expansion at Pi followed by an isochoric (isovolumetric) process at volume Vf. The amount of heat supplied to the system in the two-step process is approximately:

A
112 J
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B
294 J
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C
588 J
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D
813 J
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Solution

The correct option is C 588 J
PV5/3=C

Thus, γ=53

ΔQ1=nCPΔT=nγRγ1ΔT=γPΔVγ1=52×105(7×103)=1750 J

ΔQ2=nCVΔT=nRγ1ΔT=VΔPγ1=(1321)×105(8×103)23=93008J

ΔQ=ΔQ1+ΔQ2=175093008588 J



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