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Question

A gas is enclosed in a vessel of volume V at a pressure P. It is being pumped out of the vessel by means of a piston pump with a stroke volume V100. What is the final pressure in the vessel after n strokes of the pump? Assume no change in temperature during pumping out of gas.
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Solution

Given initial pressure =P and volume =V
Let the initial temperature be T
So, PV=nRT
Stroke volume of tyhe pump =V100
Assuming an isothermal process.
After pumping out gas of volume V100 out of V, the no. of moles left in the container =n⎜ ⎜ ⎜VV100V⎟ ⎟ ⎟=99n100
As volume V of the container is constant,
P1=P×99100
Again when gas is pumped out pressure will become P2=P1×99100=P(99100)2
After n pumping pressure inside container =P(99100)n
Hence, the answer is P(99100)n.

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