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Question

A gas is filled in a rigid container at pressure P0. If the mass of each molecule is halved keeping the total number of molecules same and their r.m.s speed is doubled then find the new pressure.

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Solution

right container = neither compressible nor expansible
As volume is constant
Maxwell's equation of his kinetic theory
PV=13nu2xmsm

PV=13MV2rms

Urms=3PVM
As P1=P0,V1=V2=V

m1=m,m2=m/2

n1=n2=n

urms1=Urms22
Now,
2Urms1=Urms2

23p1v1n1m1=3p2v2n2m2

23P0Vnm=3P2Vnm/2

4P0=2P2

P2=2P0 (Ans)

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