The correct option is D 80%
For gases, molar and volume ratios are the same at a fixed temperature and pressure.
So,if the mixture contains 1 mole of He and 1 mole of CH4.
Mass of 1 mole of CH4=16 g
Mass of 1 mole of He = 4 g
Total mass of mixture = 20 g
Percentage by mass of CH4
=mass of CH4Total mass×100=1620×100
% mass of CH4 = 80%