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Question

A gas of monoatomic hydrogen is bombarded with a stream of electrons that have been accelerated from rest through a potential difference of 12.75V. In the emission spectrum one cannot observe any line of

A
Lyman series
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B
Balmer series
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C
Paschen series
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D
Pfund series
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Solution

The correct option is C Pfund series
Energy of electron stream =12.75eV.
The ground state electron having energy 13.6eV will acquire this energy and have total energy =13.6+12.75=0.85eV.
This corresponds to the energy of electron in the 4th orbit. So, it will radiate energy when electron jumps from 4th orbit.
Hence, Pfund series cannot be observed.

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