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Question

A gaseous mixture of O2 and N2 in a closed vessel having mass 1g occupies 750mL at NTP. Volume of O2 in the mixture at NTP is?

A
400mL
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B
350mL
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C
450mL
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D
300mL
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Solution

The correct option is C 350mL
We know that
No. of moles =volumeofsolutionvolumeofsolutionatNTP
No. of moles of O2 + No. of moles of N2
Let mass of N2 is x
So, mass of O2 is 1x
Total moles =1x32+x28
So, on putting the values in formula, we have
1x32+x28=750L22.4L1000
On solving
x=0.5
So, mass of O2=10.5=0.5 g
Volume of O2 in solution
No. of moles O2=volumeofO2insolution22.4L
$ \frac {0.5} {32} = \frac {V} {22.4 L}
V=350ml

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