Physisorption | Chemisorption |
It involves physical or van der waals forces between the particles of adsorbate and adsorbent | It involves chemical bonds (covalent bonds) between adsorbate and adsorbent particles. |
It has low heat of adsorption (20-40 kJ/mol) | It has high heat of adsorption (40-200 kJ/mol) |
It is relatively weak. | It is relatively strong. |