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Question

(a) Give the molecular formula of one homologue of each of the following:
(i) C3H6
(ii) C2H6
(iii) C2H2
(b) What is the difference in the molecular mass of any two adjacent homologues?
(c) By how many carbon atoms and hydrogen atoms do any two adjacent homologues differ?

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Solution

(a)
(i) The molecular formula of a homologue of C3H6 is C4H8.​ It belongs to the homologous series of alkenes having the general formula CnH2n.
(ii) The molecular formula of a homologue of C2H6 is C3H8. It belongs to the homologous series of alkanes having the general formula CnH2n+2.
(iii) The molecular formula of a homologue of C2H2 is C3H4. I​t belongs to the homologous series of alkynes having the general formula CnH2n-2.

(b) The difference in the molecular masses of any two adjacent homologues is 14u.

(c) Any two adjacent homologues differ by 1 carbon atom and 2 hydrogen atoms in their molecular formulae.

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