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Question

A given mass of a gas is compressed isothermally until its presssure is doubled. It is then allowed to expand adiabatically until its original volume is restored and its pressure is then found to be 0.75 of its initial pressure. The ratio of the specific heats of the gas is approximately :

A
1.2
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B
1.41
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C
1.67
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D
1.83
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Solution

The correct option is B 1.41
let Initial value of volume,pressure and temperature of gas be V0, P0, T0

In step one, gas is compressed isothermally, so temperature will be constant
After first step :
Pressure = 2P0; Temperature = T0
from PV=nRT Volume = V0/2;

In 2nd step, gas is allowd to expand adiabatically to restore its original volume
After 2nd step:
Pressure = 0.75P0, Volume = V0,
from the adiabatic process relation between P and V - PVγ=constant
P1Vγ1=P2Vγ2
(V1V2)γ=P2P1

V1=V0/2, P1=2P0,
V2=V0 and P2=0.75P0

so (V0/2V0)γ=0.75P02P0
(12)γ=38
on solving this:
γ=1.41

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