The correct option is C 2.77×1021
As sample is 90% pure wrt to Gold,
So one gram of sample will have 90/100=0.9gm gold.
Number of moles of gold =Mass of goldAtomic mass of gold
=0.9197=0.0046
According to mole concept,
One mole of gold contains NA atoms =6.022×1023 atoms,
∴0.0046 mole of gold will contain =0.0046×6.022×1023
=2.77×1021