The correct option is A Carbon dioxide
Limestone contains calcium carbonate (CaCO3), which when heated at high temperature decomposes to give calcium oxide (CaO) and carbon dioxide (CO2) as shown below.
CaCO3(s) Δ→ CaO(s) + CO2(g)Calcium Calcium Carbon carbonate oxide dioxide
Greenhouse gases absorbs infrared rays from the sun and traps heat, thereby increasing the temperature of the Earth's atmosphere.
Although, carbon dioxide (CO2), methane (CH4), ozone (O3) and nitrous oxide (N2O) are greenhouse gases, only (CO2) is released during decomposition of limestone.