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Question

A greenish yellow gas X is liberated when concentrated hydrochloric acid is heated with manganese dioxide?


A

SO

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B

SO2

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C

2S

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D

Cl2

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Solution

The correct option is D

Cl2


Concentrated hydrochloric acid can readily be oxidized to chlorine by strong oxidizing agents such as manganese dioxide, lead dioxide, red lead etc. Alternatively, we can say that hydrochloric acid readily reduces these compounds.

A greenish yellow gas Cl2 is liberated when concentrated hydrochloric acid is heated with an oxidizing agent like manganese dioxide.

The gas liberated turns moist starch iodide paper blue-black.

MnO2+4HClMnCl2+2H2O+Cl2


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