Let the charge given to the conductor is Q.
All the charge will accumulate at the outer surface of the thick sphere.
Electric field near the surface is E=KQR2
For maximum charge, it should be equal to breakdown electric field.
⇒KQ(8×10−2)2=3×102
Now , maximum possible potential,
⇒V=ER=3×106×8×10−2
⇒V=3×106×8×10−2
∴V=24×104=240 kV