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Question

A hydrated salt of Na2SO3 loses 22.22% of its mass on strong heating. The hydrated salt is :

A
Na2SO3.4H2O
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B
Na2SO3.6H2O
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C
Na2SO3.H2O
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D
Na2SO3.2H2O
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Solution

The correct option is D Na2SO3.2H2O
Let the hydrated salt be Na2SO3.xH2O.
On heating, it loses water.
So, it will lose 18x g of water which is 22.22% of the total weight of the compound (given).
So, according to the given condition,
18x18x+126×100=22.22 (126 is molecular mass of Na2SO3)
x=2
So, the hydrated salt is Na2SO3.2H2O.

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