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Standard XII
Chemistry
Emission and Absorption Spectra
A hydrogen at...
Question
A hydrogen atom initially in the ground level absorbs a photon, which excites it to the
n
=
4
t
h
level. Determine the wavelength and frequency of photon.
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Solution
For ground level,
n
1
=
1
.
E
1
=
−
13.67
/
n
2
1
=
13.67
e
V
The atom is excited to higher level,
n
2
=
4
.
E
2
=
−
13.67
/
n
2
2
=
13.67
/
16
e
V
E
=
E
1
−
E
2
=
h
c
/
λ
λ
=
h
c
E
1
−
E
2
⇒
6.6
×
10
−
34
×
3
×
10
8
13.67
−
13.67
16
⇒
λ
=
97
n
m
c
=
λ
ν
⇒
ν
=
3.1
×
10
15
H
z
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