A hydrogen gas electrode is made by dipping platinum wire in a solution of HCl of pH = 10 and bypassing hydrogen gas around the platinum wire at one atm pressure. The oxidation potential of the electrode would be?
A
0.059V
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B
0.59V
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C
0.118V
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D
1.18V
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Solution
The correct option is C0.59V pH=10pH=−log[H+][H+]=10−1012H2→H++e−E=E0−0.05911log[H+]f1/2H2f1/2H2=P1/2H2=(1)1/2=1E=0−0.05911log10−10=0.59V