a) i) Explain the preparation of phenol from cumene. ii) Complete the reaction (please find above image). b) Explain Williamson's ether synthesis.
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Solution
a) i) The air oxidation of cumene (isopropyl benzene) leads to the
production of both phenol and acetone, as shown in the following figure. The
mechanisms for the formation and degradation of cumene hydroperoxide require
closer looks, which are provided following the figure. ii) C6H5OH+Zn→C6H6+ZnO b) The Williamson ether synthesis is a reaction, forming an
ether from an organohalidecompound and a deprotonated alcohol (alkoxide). R−O−+R−X→R−O−R+X−