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Question

A known mass of NaOH is dissolved in water to make 1 litre of the solution. 10 mL of the solution requires 20 ml of 1 M HCl. Molar mass of NaOH is 40 g/mol. The number of grams of NaOH in the original solution is

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Solution

Moles of HCl = Volume of HCl in L×Molarity
= 0.02×1=0.02 mol
From the stoichiometric balanced equation,
HCl+NaOHNaCl+H2O
Number of moles of HCl = Number of moles of NaOH
Hence, number of moles of NaOH present in 10 mL solution = 0.02 mol
Number of moles present in one litre = 0.02×100010 = 2 mol
Number of grams = moles × molecular weight = 2×40 = 80 g


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