A list of species having the formula $X Z_{4}$ is given below. $X e F_{4}, S F_{4}, S i F_{4}, B F_{4}^{⊖}, [C u (N H_{3})_{4}]^{2 +}, [F e C l_{4}]^{2 -}, [C o C l_{4}]^{2 -} a n d [P t C l_{4}]^{2 -} .$
Defining shape on the basis of the location of X and Z atoms, the total number of species having a square planar shape is___.
(IIT-JEE Advaced, 2014)

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Solution

$X e F_{4}, B r F_{4}^{⊖}, [C u (N H_{3})_{4}]^{+ 2}, [P t C l_{4}]^{2 -}$

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X Z_{4}

X e F_{4}, S F_{4}, S i F_{4}, B F_{4}^{-}, B r F_{4}^{-}, [C u (N H_{3})_{4}]^{2 +}, [F e C l_{4}]^{2 -}, [C o C l_{4}]^{2 -} and [P t C l_{4}]^{2 -} .

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X e F_{4}, S F_{4}, S i F_{4}, B F_{4}^{-}, B r F_{4}^{-}, [C u (N H_{3})_{4}]^{2 +}, [F e C l_{4}]^{2 -}, [C o C l_{4}]^{2 -}

[P t C l_{4}]^{2 -}

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S i F_{4}, S F_{4}, X e F_{4}, B r F_{4}^{-}, B F_{4}^{-}, [C u (N H_{3})_{4}]^{2 +}, [F e C l_{4}]^{-}, [N i (C O)_{4}]

[P t C l_{4}]^{2 -}

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X

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S F_{4}, B F_{4}^{-}, C l F_{3}, A s F_{3}, P C l_{5}, B r F_{5}, X e F_{4}, S F_{6}

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