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Question

A magnetic moment of 1.73 BM will be shown by which one among the following?

A
[Cu(NH3)4]2+
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B
[Ni(CN)4]2
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C
TiCl4
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D
[CoCl6]4
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Solution

The correct option is A [Cu(NH3)4]2+
A magnetic moment of 1.73 BM will be shown by [Cu(NH3)4]2+.
Magnetic moment is given by the expression (μ)=n(n+2)
1.73=n(n+2)
n=1
So, compound must contain one unpaired electron. The compound is [Cu(NH3)4]2+ as Cu2+ has 3d9 electronic configuration.

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