We know that,
When two coins are tossed simultaneously, the possible outcomes are (H,H),(H,T),(T,H),(T,T)
So, n(S)=4
The outcomes favorable to the event E, ‘at most one head’ are (T,H),(H,T),(T,T)
So, the number of outcomes favorable to E is 3=n(E)
Hence,P(E)=n(E)/n(S)=3/4