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Question

A mass of 50g of water in a closed vessel with surroundings at a constant temperature takes 2 minutes to cool from 30oC to 25oC. A mass of 100g of another liquid in an identical vessel with identical surroundings takes the same time to cool from 30oC to 25oC. The specific heat of the liquid is : (The water equivalent of the vessel is 30g)

A
2.0kcal/kg
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B
7kcal/g
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C
3kcal/kg
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D
0.5kcal/kg
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Solution

The correct option is D 0.5kcal/kg
As the surrounding is identical, vessel is identical time taken to cool both water and liquid (from 30C to 25C) is same 2 minutes.

(dQdt)water=(dQdt)liquid

Or (mwcw+W)ΔT1t1=(mlcl+W)ΔT2t2

ΔT1=ΔT2,t1=t2

(w = water equivalent of the vessel)

or mwcw=mlcl

specific heat of liquid,

Cl=mwcwml=50×1100=0.5kcal/kg

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