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Question

A metal carbonate, on being heated strongly gives a solid that forms a green solid with CoO. In which analytical group will the cation be precipitate and what will be the colour of the precipitate?

A
Group I, white
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B
Group II, yellow
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C
Group III, white
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D
Group IV, white
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Solution

The correct option is D Group IV, white
ZnO forms a green solid with CoO.
ZnO+CoOCoZnO2 cobalt zincate (green)
ZnO is obtained when zinc carbonate is heated.
ZnCO3ΔZnO+CO2
Zn2+ belongs to fourth group. It is precipitated as white precipitate of ZnS (zinc sulphide) that is insoluble in ammonium hydroxide.

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