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Question

A metal carbonate X on reacting with an acid gives a gas which when passed through a solution Y gives the carbonate back. On the other hand, a gas G that is obtained at the anode during electrolysis of brine is passed on dry Y, it gives a compound Z, used for disinfecting drinking water. Identify X, Y, G and Z.

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Solution

X is calcium carbonate and the gas evolved is carbon dioxide, when calcium carbonate reacts with acid.

CaCO3+Dil.2HClCaCl2+H2O+CO2

Solution Y is lime water Ca(OH2) because, when CO2 is passed through it, it gives the carbonate back as shown by the given equation.

Ca(OH)2Y+CO2CaCO3X+H2O

The gas evolved at anode during electrolysis of brine is chlorine (G).

2NaClSodium chloride (brine)+2H2OElectrolysis2NaOH+Cl2(g)Chlorine gas (G)+H2(g)

When chlorine gas is passed through dry Ca(OH)2 (Y), it produces bleaching powder (Z) used for disinfecting drinking water.

Ca(OH2)+Cl2CaOCl2Bleaching powder (Z)+H2O

Hence, Z is calcium oxy-chloride CaOCl2 or bleaching powder.

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