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Question

A metal hydroxide is precipitated as a white gelatinous substance when NH4OH is added to the solution (after previously removing acid insoluble sulphides with H2S). The metal in metal hydroxide is :

A
Cr
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B
Fe
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C
Al
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D
Zn
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Solution

The correct option is D Al
Al3++3OHAl(OH)3Whiteppt

An excess of regent dissolves the precipitate forming tetrahydroxoaluminate
Al(OH)3+3OH[Al(OH)4]

Addition of NH4OH further gives gelatinoius white ppt. of Aluminum hydroxide.
[Al(OH)4]+NH+4Al(OH)3+NH3+H2O

Option C is correct.

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