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Question

A metal ion Mn+ having d4 valence electronic configuration combines with three bidentate ligands to form a complex compound. Assuming a>p:
(i) Write the electronic configuration of d4 ion.
(ii) What type of hybridisation will Mn+ ion has?
(iii) Name the type of isomerism exhibited by this complex.

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Solution

(i) Since P<oso, pairing of electrons takes place and d4 exists as t42gego.
(ii)Then hyfridisation is d2Sp3 due to vaccant two inner d orbital.
(iii)[M(AA)3]n+ shows optical isomerism due to plane to symmetry.

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