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Question

A metal nitrate reacts with KI to give a black precipitate which on addition of excess of KI converts to an orange color solution. The cation of metal nitrate is :

A
Hg2+
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B
Bi3+
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C
Pb2+
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D
Cu+
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Solution

The correct option is B Bi3+
Option (B) is correct.
The cation of metal nitrate is Bi3+.
Bi3++3KIBiI3+3K+Black

BiI3+KIK[BiI4]Orangesolution

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