The metal or metallic substances used to construct a thermionic emitter should have some main features.
It should have a low work function.
A low work function helps to emit electrons from the cathode surface in a comparatively lower temperature.
It should have a high melting point.
Tungsten metal is used as an electron emitter as it has a very high melting point () and moderate work function.
It has a work function of about . It starts emission at .
If thoriated tungsten (which is coated with carbon and thorium) is used work function reduces to and emission begins at .
If tungsten is coated with metals like barium and strontium oxide work, function reduces to and emission begins at and a good quality of electrons is obtained.