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Question

A metallic calorimeter of mass 100g contains 200 g of ice and the initial temperature of the calorimeter and the ice is 10C. Heat is supplied to the system containing calorimeter and ice at a constant rate of 50 cals1. Find the time required to raise the temperature of the system to 50C. [Neglect the loss of heat to the surroundings].
Take specific heat capacity of calorimeter and ice as 0.2calg1C1 and 12calg1C1.Take latent heat of fusion of ice as 80calg1 and specific heat capacity of water as 1calg1C1

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Solution

Given data:
Mass of calorimeter = 100gm
Mass of ice =200gm
initial temperature of calorimeter + ice =10oC
Rate of heat supplied to calorimeter=50cals1
Final temperature of system(calorimeter+ice)=50oC
Specific heat of calorimeter =0.2calg1oC1
specific heat of ice =12calg1oC1
Latent heat of fusion =80cal/gm
Specific heat capacity of water =1calg1oC1
Now in the question:
temperature of the system is changed from 10oC to 50oC
It means heat is supplied to the system for
(1) heat required to change the temperature of calorimeter from 10oC to 50oC

Now
Q1=mcT
=100×0.2×60=1200calories

(2) heat required to change the temperature of ice from 10oCto0oC
heat required =mcΔT
Q2=200×12×10=1000calories

(3) Heat required to change the state of ice i.e from solid to liquid (ice converted to water)
Q3=mL
where L =latent of heat
Q3=200×80=16000calories

(4) Heat required to change the temperature of water from 0C0to50oC
Q4=mcΔT = 200×1×50=10000calories
Total heat needed to convert the temperature of substance=Q1+Q2+Q3+Q4
Q=1200+1000+16000+10000=28200calories
But we are given rate of heat supplied =50cal/s
50 calories are supplied in = 1s
1 calorie is supplied in =150s
28200 calories are supplied in =(150×28200)s=564seconds
Hence, the answer is 564 seconds

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