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Question

A metallic fluoride contains 67.78% fluorine. One mole of that compound contains 1.5 times the number of atoms in one mole of dry fluorine gas. Find the atomic weight of the metal.

A
27 gm
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B
54 gm
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C
13.5 gm
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D
none of these
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Solution

The correct option is A 27 gm
Given,
67.8 g fluorine is present in 100 g of metallic fluoride
1 mole of fluorine gas - 2 N fluorine atoms
Numberoffluorineionsinonemoleofcompound=1.5×2N=3N
TheformulaofthecompoundMF3
57gfluorineispresentin1moleofMF3
67.8gfluorine100gMF3
57gfluorine570067.8=84gm
Mass of MF3=84gm=x+193
Atomicweightofmetal=27g

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