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Question

A mixture (by weight) of hydrogen and helium is enclosed in a two-litre flask at 27oC. Assuming ideal kept behaviour, the partial pressure of helium is found to be 0.2atm. Then the concentration of hydrogen would be:

A
0.045
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B
8.26
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C
0.0162
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D
1.62
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Solution

The correct option is C 0.0162
Given, H2 and He gas mixture is enclosed in a flask.

V=2LT=300K
It is given, Partial pressure of He is 0.2 atm .

so, nHe =PHe VRT=0.2×20.0821×300 moles

=0.01624 moles.
Since, mixture constitutes 1:1H2 - He ratio by weight.
Thus, weight of H2=0.01624×4gm=0.06496gm

moles of H2=0.03248mol

so, concentration of H2= moles volume =0.032482=0.01624M

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