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Question

A mixture is prepared by mixing 10 g H2SO4 and 40 g SO3. The mole fraction of H2SO4 and % labelling of oleum is :

A
0.169,118%
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B
0.169,108%
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C
0.184,118%
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D
0.184,108%
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Solution

The correct option is D 0.169,118%
Mole fraction of H2SO4=10981098+4080=0.169
We know, percent labeling of oleum = total mass of H2SO4 present in oleum after dilution = mass of H2SO4 initially present + mass of H2SO4 produced on dilution.

T
otal mass of H2SO4 present in oleum after dilution =98w80+(100w)=% label.
So, total mass of H2SO4 present in oleum after dilution =98×8080+(10080)=118, where w is weight of SO3 in original mixture.

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