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Question

A mixture of 0.3 mole of H2 and 0.3 mole of I2 is allowed to react in a 10 litre evacuated flask at 500C. The reaction is H2+12HI the K is found to be 64. The amount of unreacted 12 at equilibrium is ?

A
0.1 mole
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B
0.06 mole
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C
0.03 mole
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D
0.02 mole
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Solution

The correct option is B 0.06 mole
solution:
H2 + I2 2HI
Initial 0.3 0.3 --
At Equilibrium (0.3−x) (0.3−x) 2x
KC=[HI]2[H2][I2]

64=[2x10][0.3x10][0.3x10]

60x238.4x+5.76=0

x=0.24
Hence,moles of I2 unreacted =0.3−0.24=0.06 mole.
hence the correct option :B

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