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Question

A mixture of 1.57 mol of N2,1.92 mol of H2 and 8.13 mol of NH3 is introduced in a 20L reaction vessel at 500K.At this temperature the equilibrium constant, Kc for the reaction N2(g)+3H2(g)2NH3(g) is 1.7×102.

Is the reaction mixture at equilibrium? If not what is the direction of net reaction?

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Solution

N2(g)+3H2(g)=2NH3(g)
so, reaction quotient (Qc)=[NH3]2[H2]3[N2]

Given ,
[NH3]=8.13mol/20L { concentration = mole/volume }
= 0.4065M

[N2]=1.57mol/20L=0.0785M

[H2] =1.92mol/20L=0.096M

Qc=(0.4065M)2(0.096M)3(0.0785M)
=2.379×103/M2

Here, you can see that , Kc is not equal to Qc , so the reaction is not in equilibrium.

because Qc>Kc it means that the reaction will proceed in backward direction or in the direction of reactants .

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