A mixture of 10g of hydrogen and 40g of helium are kept in a closed vessel. To change the temperature of the mixture by 50∘C, the amount of heat energy should be added to the mixture is
(Given R=2cal mol−1∘C−1)
A
2500cal
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B
2000cal
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C
2750cal
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D
None of these
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Solution
The correct option is C2750cal Given,
Weight of hydrogen =10g
Weight of helium =40g
No. of moles of hydrogen (n1)=102=5
No. of moles of helium (n2)=404=10
Since, hydrogen is diatomic and helium is monoatomic, we get (CV)1=5R2 (CV)2=3R2
We know that, (CV)mixture=n1CV1+n2CV2n1+n2 =5(5R2)+10(3R2)15 =11R6 ∴ΔQ=n(CV)mixtureΔT=15×11×2×506=2750cal