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Question

A mixture of 254 g of iodine and 142 g of chlorine is made to react completely to given a mixture of ICl and Icl3. How many moles of each product are formed?
(I=127,Cl=35.5).

A
0.1 mol of ICl and 0.1 mol of ICl3
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B
1.0 mol of ICl and 1.0 mol of ICl3
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C
0.5 mol of ICl and 0.1 mol of ICl3
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D
0.5 mol of ICl and 1.0 mol of ICl3
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Solution

The correct option is A 0.1 mol of ICl and 0.1 mol of ICl3
Given,
Mass of Iodine=254g
Mass of Chlorine=142g
The reaction involved
I2+2Cl2ICl+ICl3
Moles of Iodine provided=254g254g/mole=1 mole
Moles of Chlorine provided=142g71g/mole=2 mole
Molar mass of I2254g/mole
Molar mass of Cl2=71g/mole
Now, from reaction it is clear that
1 mole of I2+2 mole of Cl2 will produce
1 mole ICl & 1 mole ICl3
So we are provided with 1 mole I2 & 2 mole Cl2
Product formed with
ICl=1 mole
ICl3=1 mole

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