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Question

A mixture of hydrogen and chlorine occupying 36cc was exploded. On shaking it with water, 4cc of hydrogen was left behind. Find the composition of the mixture.

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Solution

Hydrogen and chlorine when reacted together form Hydrogen chloride (HCl).
H2+Cl22HCl
When mixed with water, HCl dissolves in water.
HCl+H2OH3O+Cl
Now, the point is, that the excess hydrogen left after dissolving in water is the unreacted hydrogen.
Now, H2+Cl22HCl
So, 1 mole of H2
reacts with Cl2
1 mole of every gas occupies 22.4 litres at room teperature.
So, 22.4 litre of H2 reacts with Cl2
1 litre of H2 reatcs with Cl2
1 cc ofH2 reacts with 1 cc ofCl2
Total volume initially was 36 cc, and H2 left at last was 4 cc.
So, 36 - 4 =32 cc of volume of mixture reacted.
1 cc of H2 reacts with 1 cc of Cl2, so out of the 32 cc 16 cc was H2 and 16 cc was Cl2
So, mixture had 16 + 4 = 20 cc H2 and 16 cc of Cl2

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