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Question

A mixture of two immiscible liquids at a constant pressure of 1.0 atm boils at temperature

A
Equal to the normal boiling point of more volatile liquid.
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B
Equal to the mean of the normal boiling points of two liquids.
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C
Greater than normal boiling point of either of liquids.
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D
Smaller than the normal boiling point of either of liquids.
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Solution

The correct option is D Smaller than the normal boiling point of either of liquids.
As we know, a solute (non volatile) lowers the vapour pressure of a liquid ,and hence a higher boiling point the solution.
so here, mixture will boil at lower temperature of the boiling point of either liquid.

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