For T.I.R at coating
sinc=n√3
Appling snell's law at first surface
sinθ=√3sin(75−c)
for limiting condition, at θ=60o
sin60=√3sin(75−c)
√32=√3sin(75−c)
12=sin(75−c)⇒sin30=sin(75−c)
30=75−c⇒c=45o
Since, sinc=n√3
n√3=1√2⇒n2=32=1.50