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Question

(a) Name an element which reacts with hydrogen to form a compound which is strongly acidic in water.
(b) Explain why dilute hydrochloric acid cannot be concentrated by boiling beyond 22.2%.

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Solution

(a) Chlorine.
The compound formed which is strongly acidic in water is HCl.
H2+Cl22HCl
(b) A dilute aqueous solution of hydrochloric acid gets gradually concentrated on distillation until the concentration of the acid reaches 22.2% HCl by weight which boils at 110oC. When this concentration is reached, no further increase in the concentration of the acid becomes possible by boiling. This is because vapours evolved before 110oC are vapours of water but at the temperature above 110oC consist mostly of molecules of HCl.


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