The correct option is D 322
Potential difference across capacitor C4 is V.
So, the charge on C4 be
Q4=C4V
As, C4=4C
⇒Q4=4CV
Since, C1, C2 and C3 are in series connection so, their equivalent capacitance will be
1Ceq=1C1+1C2+1C3
⇒1Ceq=1C+12C+13C
⇒Ceq=6C11
So, the charge across the C2 will be
Q2=CeqV
⇒Q2=6CV11
So, the ratio of the charges on C2 and C4
Q2Q4=6CV/114CV=322
Hence, option (d) is the correct answer.