.
Applying conservation of linear momentum in horizontal direction
(Initial Momentum )x = (Final Momentum)x
(P1)x=(Pf)x
⇒√2Km=√2(4m)K1cosθ…(i)
Now applying conservation of linear momentum in Y – direction
(Pi)y=(Pf)y
=√2K2m−√2(4m)K1sinθ
→√2K2m=√2(4m)K1sinθ….(ii)
Squaring and adding (i) and (ii)
2Km+2Km2m=2(4m)K1+2(4m)K1
K1+K2=4K1⇒K=4K1–K2⇒4K1–K2=65…(iii)
When collision takes place, the electron gains energy and jumps to higher orbit.
Applying energy conservation
K=K1+K2+ΔE
65=K1+K2+ΔE
Possible value of ΔE for He+
Case (1)
ΔE1=−13.6–(−54.4)=40.8eV
K1+K2=24.2eV from (4)
Solving with (3), we get
K2=6.36eV;K1=17.84eV
Case (2)
ΔE2=−6.04–(−54.4)=48.36eV
K1+K2=16.64eV from (4)
Solving with (3), we get K2=0.312eV;K1=16.328eV
ΔE3=−3.4–(−54.4)=51.1eV
⇒K1+K2=14eV
Solving with (3), we get
K2=15.8eV;K1=−1.8eV
But K.E. can never be negative therefore case (3) is not possible.
Therefore, the allowed values of kinetic energies are only that of case (1) and case (2) and electron can jump upto n = 3 only.
(ii) Thus when electron jumps back there are three possibilities
n3 → n1 or n3 →n2 and n2 → n1
The frequencies will be
y1=E3–E2/h
v2=E3–E1/h
v3=E2–E1/h
1.82 x 1015Hz;
11.67 x 1015Hz;
9.84 x 1015Hz