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Question

A nitrate of an alkali metal M on heating gives O2.NO2 and M2O. The metal M will be:

A
Na
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B
K
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C
Rb
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D
Li
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Solution

The correct option is D Li
All group 1 compounds (metal nitrates) decompose to give metal nitrates and
oxygen
2MNO32MNO2+O2
Since Lithium shows diagonal relationship with magnesium, it shows different behaviour
4LiNO32Li2O+4NO2+O2
(It's nitrate decomposes like Group 2 elements)

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