A numismatist (coin collector) has been collecting gold coins, silver coins and copper coins for a long time. One day he observed a black coating on silver coins and green coating on copper coins. Which chemical process is responsible for these coatings?
The coating occurred due to a chemical process called corrosion. Black coating is due to deposit of Silver Sulphide (Ag2S). Green coating is due to formation of Copper Carbonate (CuCO3).
2Ag(s) + H2S(g) → Ag2S(s) + H2(g)
(Note: Silver usually is corrosion resistant and does not oxidize. However presence of sulphur gases in atmosphere can react and cause sulphur-corrosion).