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Question

A photon having λ=800 A causes the ionization of a nitrogen atom. The I.E. per mole of nitrogen in KJ is?
[Given:E=1240 eVnm,1eV=96.43 KJ/mol]

A
1495.42 KJ/mol
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B
1500.56 KJ/mol
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C
1634.87 KJ/mol
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D
1567.32 KJ/mol
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Solution

The correct option is A 1495.42 KJ/mol
The energy of one photon of wavelength 800 A is:

E=hcλ=6.6256×1034Js×2.9979×108m/s800×1010m

=2.476×1018J=2.47×1021kJ

The energy for one mole of photons is:

E=6.023×1023×2.476×1021kJ

=1495.42kJ/mol.

Hence, the correct option is A

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